Structure-directing role of amines in the ionothermal synthesis.

Ionothermal synthesis of AlPO4-34 molecular sieves using heterocyclic aromatic amine as the structure directing agent

Ionothermal synthesis of aluminophosphate molecular sieve membranes through substrate surface conversion.

Applications of zeolite membranes in separation, chemical sensors, and catalytic membrane reactors have led to extensive studies on their fabrication. To date, mainly silicatebased zeolite membranes of the structure types MFI, DDR, LTA, and FAU have been synthesized on different substrates and evaluated for singleor multiple-gas permeation. Routes for the synthesis of zeolite membranes can be b...

THE ROLE OF AMINES AS TEMPLATES IN DIRECTING THE STRUCTURE OF ZEOLITES

In this article, we have investigated the role of dimethylamine (DMA), tributylamine (TBA), Triethanoleamine (TEA), Trishydroxymethylamine (TRIZMA), and Hexamethyleneterraamine (HMTA), in the formation of zeolitic compounds. The experiments were carried out in acidic and basic media using Si/Al< 10 and Si/A1>10. The structure of the resulting synthetic zeolites were similar to Natro Davyne,...

Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers.

Four new cobalt coordination polymers, (EMIm)[Co2(TMA-H)2(44bpy)3]Br 1, (EMIm)[Co(TMA-H)(44bpy)2](44bpy)Br 2, (EMIm)[Co(TMA)(Im-H)]3 and (EMIm)2[Co(TMA)2(TED-H2)] 4, were prepared from 1-ethyl-3-methyl imidazolium bromide (EMIm-Br). All the compounds have similar two-dimensional cobalt trimesate (TMA) coordination layers but different three-dimensional supramolecular architectures that contain ...

Ionothermal synthesis of aluminophosphate molecular sieves

Effects of ionic liquid structures on the aluminophosphate molecular sieve products in ionothermal synthesis process were investigated. The results showed that the possible structure-directing effect of ionic liquid might exist during ionothermal synthesis. Microwave heating was introduced into the ionothermal synthesis, which led to a fast and safe process for preparation of molecular sieves. ...